Guide to World Crudes: TotalEnergies issues assay for Brazilian Atapu

Dec. 6, 2021
In July 2021, TotalEnergies SE published an assay dated Apr. 27, 2021, for Atapu crude oil, produced from the Iara cluster in the eastern portion of Brazil’s deepwater Santos basin presalt.

In July 2021, TotalEnergies SE published an assay dated Apr. 27, 2021, for Atapu crude oil, produced from the Iara cluster in the eastern portion of Brazil’s deepwater Santos basin presalt.

Operator Petróleo Brasileiro SA (Petrobras) began producing crude oil and natural gas in June 2020 from its P-70 floating production, storage, and offloading vessel (FPSO) stationed in Atapu field (OGJ Online, June 26, 2020).

In 2,300 m of water about 200 km off Rio de Janeiro state, the P-70 FPSO reached its full oil production capacity of 150,000 b/d in July 2021 producing from only four of its eight planned production wells, Petrobras said in a July 23, 2021, release.

Built by China National Offshore Oil Corp. (CNOOC) subsidiary CNOOC Engineering Co. Ltd. and measuring 300-m long by 74-m wide, the P-70 FPSO is also equipped to process 6 million cu m/day of gas.

In addition to Petrobras (89.257%), partners with rights to Atapu deposits include Shell Brasil Petróleo Ltd. (4.258%), TotalEnergies EP Brasil Ltd. (3.832%), Petrogal Brasil SA (1.703%) and Pré-Sal Petróleo SA (0.950%).

Whole crude

Density at 15° C., kg/cu m.: 885.1

Gravity, °API: 28.3

Acidity, mg KOH/g: 0.24

Sulfur, wt %: 0.37

Mercaptan sulfur, mg/kg: 35

Viscosity at 10° C., cst: 81.6

Viscosity at 50° C., cst: 14.3

Pour point, °C.: -18

Total nitrogen, wt %: 0.26

Basic nitrogen, wt %: 0.13

Sodium chloride, mg/kg: 3.0

Nickel, mg/kg: 10.9

Vanadium, mg/kg: 12.8

Iron, mg/kg: 6.2

Calcium, mg/kg: < 1

Silicium, mg/kg: < 3

Zinc, mg/kg: 6.5

Propane, wt %: 0.3

Propane, vol %: 0.5

iso-Butane, wt %: 0.2

iso-Butane, vol %: 0.3

n-Butane, wt %: 0.6

n-Butane, vol %: 0.9

Light naphtha, 15-65° C.

Yield on crude, wt %: 2.3

Yield on crude, vol %: 3.1

Density at 15° C., kg/cu m.: 648

Sulfur, wt %: 0.02

Mercaptan sulfur, mg/kg: 7

Research octane no., clear: 70.4

Motor octane no., clear: 69.2

Naphthenes, vol %: 7.5

Aromatics, vol %: 0.5

Light naphtha, 15-80° C.

Yield on crude, wt %: 3.2

Yield on crude, vol %: 4.2

Density at 15° C., kg/cu m.: 662

Sulfur, wt %: 0.02

Mercaptan sulfur, mg/kg: 16

Research octane no., clear: 67.4

Motor octane no., clear: 65.8

Naphthenes, vol %: 14.2

Aromatics, vol %: 1.4

Heavy naphtha, 80-150° C.

Yield on crude, wt %: 7.6

Yield on crude, vol %: 9.0

Density at 15° C., kg/cu m.: 745

Sulfur, wt %: 0.03

Mercaptan sulfur, mg/kg: 57

Naphthenes, vol %: 49.4

Aromatics, vol %: 7.1

Heavy naphtha, 80-175° C.

Yield on crude, wt %: 10.6

Yield on crude, vol %: 12.5

Density at 15° C., kg/cu m.: 755

Sulfur, wt %: 0.03

Mercaptan sulfur, mg/kg: 57

Naphthenes, vol %: 50.0

Aromatics, vol %: 8.4

Heavy naphtha, 100-150° C.

Yield on crude, wt %: 6.0

Yield on crude, vol %: 7.0

Density at 15° C., kg/cu m.: 753

Sulfur, wt %: 0.03

Mercaptan sulfur, mg/kg: 58

Naphthenes, vol %: 51.3

Aromatics, vol %: 7.6

Kerosine, 150-230° C.

Yield on crude, wt %: 9.5

Yield on crude, vol %: 10.5

Density at 15° C., kg/cu m.: 801

Sulfur, wt %: 0.08

Mercaptan sulfur, mg/kg: 45

Smoke point, mm: 24

Acidity, mg KOH/g: 0.08

Cetane index 1990 (D-4737): 40.1

Freeze point, °C.: -53

Aromatics, vol %: 15.1

Viscosity at 50° C., cst: 1.0

Flash point, °C.: 55.9

Kerosine, 175-230° C.

Yield on crude, wt %: 6.5

Yield on crude, vol %: 7.1

Density at 15° C., kg/cu m.: 810

Sulfur, wt %: 0.09

Mercaptan sulfur, mg/kg: 40

Smoke point, mm: 24

Acidity, mg KOH/g: 0.09

Cetane index 1990 (D-4737): 41.2

Freeze point, °C.: -48

Aromatics, vol %: 16.6

Viscosity at 50° C., cst: 1.2

Flash point, °C.: 69.4

Kerosine, 150-250° C.

Yield on crude, wt %: 12.2

Yield on crude, vol %: 13.4

Density at 15° C., kg/cu m.: 807

Sulfur, wt %: 0.09

Mercaptan sulfur, mg/kg: 41

Smoke point, mm: 24

Acidity, mg KOH/g: 0.09

Cetane index 1990 (D-4737): 41.9

Freeze point, °C.: -48

Aromatics, vol %: 16.2

Viscosity at 50° C., cst: 1.1

Flash point, °C.: 59.2

Gas oil, 175-400° C.

Yield on crude, wt %: 32.3

Yield on crude, vol %: 33.4

Density at 15° C., kg/cu m.: 855

Sulfur, wt %: 0.20

Aniline point, °C.: 67

Cetane index 1990 (D-4737): 48.7

Cloud point, °C.: -2

Cold filter plugging point, °C.: -5

Pour point, °C.: -9

Viscosity at 50° C., cst: 3.2

Viscosity at 100° C., cst: 1.4

UOP K factor: 11.8

Flash point, °C.: 84.4

Gas oil, 230-400° C.

Yield on crude, wt %: 25.8

Yield on crude, vol %: 26.3

Density at 15° C., kg/cu m.: 868

Sulfur, wt %: 0.23

Aniline point, °C.: 69

Cetane index 1990 (D-4737): 51.0

Cloud point, °C.: 1

Pour point, °C.: -1

Viscosity at 50° C., cst: 4.5

Viscosity at 100° C., cst: 1.8

UOP K factor: 11.8

Flash point, °C.: 107.7

Gas oil, 230-375° C.

Yield on crude, wt %: 21.9

Yield on crude, vol %: 22.4

Density at 15° C., kg/cu m.: 861

Sulfur, wt %: 0.21

Aniline point, °C.: 68

Cetane index 1990 (D-4737): 51.3

Cloud point, °C.: -4

Cold filter plugging point, °C.: -5

Pour point, °C.: -6

Viscosity at 50° C., cst: 3.7

Viscosity at 100° C., cst: 1.6

UOP K factor: 11.8

Flash point, °C.: 105.7

Vacuum distillate, 375-550° C.

Yield on crude, wt %: 27.1

Yield on crude, vol %: 25.8

Density at 15° C., kg/cu m.: 929

Sulfur, wt %: 0.40

Conradson carbon residue, wt %: 0.2

Aniline point, °C.: 83

Total nitrogen, wt %: 0.25

Basic nitrogen, mg/kg: 953

Pour point, °C.: 38

Viscosity at 100° C., cst: 12.0

Viscosity at 150° C., cst: 4.0

UOP K factor: 11.8

Vacuum distillate, 375-565° C.

Yield on crude, wt %: 29.2

Yield on crude, vol %: 27.7

Density at 15° C., kg/cu m.: 931

Sulfur, wt %: 0.41

Conradson carbon residue, wt %: 0.4

Aniline point, °C.: 83

Total nitrogen, wt %: 0.26

Basic nitrogen, mg/kg: 1,020

Pour point, °C.: 39

Viscosity at 100° C., cst: 13.2

Viscosity at 150° C., cst: 4.3

UOP K factor: 11.8

Vacuum distillate, 375-580° C.

Yield on crude, wt %: 31.3

Yield on crude, vol %: 29.6

Density at 15° C., kg/cu m.: 933

Sulfur, wt %: 0.42

Conradson carbon residue, wt %: 0.5

Aniline point, °C.: 83

Nickel, mg/kg: 1.0

Vanadium, mg/kg: 1.0

Total nitrogen, wt %: 0.27

Basic nitrogen, mg/kg: 1,090

Pour point, °C.: 40

Viscosity at 100° C., cst: 14.5

Viscosity at 150° C., cst: 4.6

UOP K factor: 11.8

Asphaltenes (C7), wt %: 0.1

Vacuum distillate, 400-580° C.

Yield on crude, wt %: 27.3

Yield on crude, vol %: 25.7

Density at 15° C., kg/cu m.: 938

Sulfur, wt %: 0.43

Conradson carbon residue, wt %: 0.6

Aniline point, °C.: 85

Nickel, mg/kg: 1.0

Vanadium, mg/kg: 1.0

Total nitrogen, wt %: 0.29

Basic nitrogen, mg/kg: 1,200

Pour point, °C.: 42

Viscosity at 100° C., cst: 18.0

Viscosity at 150° C., cst: 5.4

UOP K factor: 11.8

Asphaltenes (C7), wt %: 0.1

Residue, > 375° C.

Yield on crude, wt %: 56.7

Yield on crude, vol %: 52.0

Density at 15° C., kg/cu m.: 964

Sulfur, wt %: 0.56

Conradson carbon residue, wt %: 7.6

Acidity, mg KOH/g: 0.2

Nickel, mg/kg: 19.0

Vanadium, mg/kg: 23.0

Total nitrogen, wt %: 0.44

Pour point, °C.: 30

Viscosity at 100° C., cst: 93

Viscosity at 150° C., cst: 17

Asphaltenes (C7), wt %: 1.4

Residue, > 550° C.

Yield on crude, wt %: 29.6

Yield on crude, vol %: 26.2

Density at 15° C., kg/cu m.: 998

Sulfur, wt %: 0.70

Conradson carbon residue, wt %: 14.2

Acidity, mg KOH/g: 0.2

Nickel, mg/kg: 37.0

Vanadium, mg/kg: 43.0

Total nitrogen, wt %: 0.61

Pour point, °C.: 62

Viscosity at 100° C., cst: 2,210

Viscosity at 150° C., cst: 149

Penetration, mm/10: 64

Asphaltenes (C7), wt %: 2.6

Residue, > 565° C.

Yield on crude, wt %: 27.5

Yield on crude, vol %: 24.3

Density at 15° C., kg/cu m.: 1,001

Sulfur, wt %: 0.72

Conradson carbon residue, wt %: 15.2

Acidity, mg KOH/g: 0.2

Nickel, mg/kg: 39.0

Vanadium, mg/kg: 46.0

Total nitrogen, wt %: 0.63

Pour point, °C.: 64

Viscosity at 100° C., cst: 3,270

Viscosity at 150° C., cst: 194

Penetration, mm/10: 53

Asphaltenes (C7), wt %: 2.8

Residue, > 580° C.

Yield on crude, wt %: 25.4

Yield on crude, vol %: 22.4

Density at 15° C., kg/cu m.: 1,004

Sulfur, wt %: 0.73

Conradson carbon residue, wt %: 16.2

Acidity, mg KOH/g: 0.2

Nickel, mg/kg: 42.0

Vanadium, mg/kg: 49.0

Total nitrogen, wt %: 0.64

Pour point, °C.: 65

Viscosity at 100° C., cst: 5,010

Viscosity at 150° C., cst: 258

Penetration, mm/10: 46

Asphaltenes (C7), wt %: 3.0

Atapu assay from TotalEnergies SE at TotalEnergies Trading & Shipping website.